Sulfuric acid as a corrosive cryofluid and oxygen isotope reservoir in planetesimals
نویسندگان
چکیده
The Sun exhibits a depletion in $^{17,18}$O relative to $^{16}$O by 6 % compared the Earth and Moon$^{1}$. origin of such non-mass-dependent isotope fractionation has been extensively debated since three-isotope-analysis$^{2}$ became available 1970's. Self-shielding$^{3,4}$ CO molecules against UV photons solar system's parent molecular cloud suggested as source effect, which $^{17,18}$O-enriched oxygen was trapped ice selectively incorporated water into planet-forming materials$^{5}$. truth is that Earth-Moon other planetary objects deviate positively from ~6 their isotopic compositions. A stunning exception magnetite/sulfide symplectite found Acfer 094 meteorite, shows 24 enrichment Sun$^{6}$. Water does not explain this high. Here we show SO SO$_2$ cloud, ~106 enriched Sun, evolved through protoplanetary disk planetesimal stages become sulfuric acid, $^{17,18}$O. acid provided cryofluid environment itself reacted with ferric iron form an amorphous ferric-hydroxysulfate-hydrate, eventually decomposed shock. We indicate Acfer-094 its progenitor, strongly coupled material evolution system days our cloud.
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Hassan Sepehrmansourie was born in Hamedan, Iran in 1994. He received his B.Sc. in Applied Chemistry (2017) from Bu-Ali Sina University, Iran. He received his M.Sc.in Organic Chemistry (2019) under the supervision of Prof. Mohammad Ali Zolfigol. Also, He was also accepted for a Ph.D. in organic chemistry at the Bu-Ali Sina University in the same year. His research interest is t...
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ژورنال
عنوان ژورنال: Icarus
سال: 2023
ISSN: ['0019-1035', '1090-2643']
DOI: https://doi.org/10.1016/j.icarus.2023.115535